The application of frontier molecular orbital theory (HOMO-LUMO interactions) to organic reactions, including thermal and photochemical cycloadditions of pi-systems (including 1,3-dipoles) and rearrangements. Reactions of radicals and carbenes; conformational analysis, stereochemical effects, and methods for the determination of reaction mechanisms. Prerequisite(s): CHEM 3202 and CHEM 3503 (may be taken concurrently).Lectures and seminars three hours a week.

CHEM 4205 [0.5 credit] Reactivity and Mechanism in Organic Chemistry

The application of frontier molecular orbital theory (HOMO-LUMO interactions) to organic reactions, including thermal and photochemical cycloadditions of pi-systems (including 1,3-dipoles) and rearrangements. Reactions of radicals and carbenes; conformational analysis, stereochemical effects, and methods for the determination of reaction mechanisms. Prerequisite(s): CHEM 3202 and CHEM 3503 (may be taken concurrently).Lectures and seminars three hours a week.





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